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二苄基碲

二苄基碲
别名 二苄基碲醚
识别
CAS号 62654-03-9  checkY
性质
化学式 C14H14Te
摩尔质量 309.86 g·mol−1
外观 浅黄色针状晶体[1]
熔点 53—53.5 °C(326.1—326.6 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二苄基碲是一种有机化合物,化学式为(C6H5CH2)2Te。它可由氯化苄水合肼氢氧化钾反应制得。[2]氯化苄、碲和碘化钠在110 °C反应,得到二苄基二碘化碲,它经硫化钠还原,也能得到二苄基碲。[3]

它和二(三氟甲基)碲反应,可以得到苄基三氟甲基碲。[4]

参考文献

  1. ^ 1.0 1.1 Chugaev, L.; Chlopin, W. Reducing power of sulfurous acid. I. Action of sodium hydrosulfite on tellurium and selenium. Berichte der Deutschen Chemischen Gesellschaft. 1914. 47: 1269-1275.
  2. ^ Korchevin, N. A.; Podkuiko, P. A.; Stankevich, V. K.; Deryagina, E. N.; Trofimov, B. A. New route to diorganyl selenides and tellurides. Zhurnal Obshchei Khimii, 1995. 65 (1): 99-101.
  3. ^ Kulkarni, Y. D., & Srivastava, S. (1985). Synthesis & Characterization of Some Stable Dibenzyltellurium (II&IV) Derivatives & Their Antibacterial Activity. Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical. 1985. 24A (8): 710-712.
  4. ^ Douglas C. Gordon, Rein U. Kirss, Duncan W. Brown. Synthesis and characterization of volatile trifluoromethyl alkyl tellurides. Organometallics. 1992-08, 11 (8): 2947–2949 [2023-03-12]. ISSN 0276-7333. doi:10.1021/om00044a043. (原始内容存档于2023-03-12) (英语). 

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