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二苄基硫醚

二苄基硫醚
IUPAC名
Benzylsulfanylmethylbenzene
别名 苄硫醚
识别
CAS号 538-74-9
PubChem 10867
ChemSpider 10407
SMILES
 
  • C1=CC=C(C=C1)CSCC2=CC=CC=C2
Beilstein 1911157
UN编号 3335
性质
化学式 C14H14S
摩尔质量 214.33 g·mol−1
熔点 49.5 °C(323 K)
沸点 322 °C(595 K)
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二苄基硫醚是一种有机硫化合物,化学式C14H14S,为无色或白色固体,可溶于非极性溶剂。

结构

二苄基硫醚是正交晶系的晶体,空间群Pbcn,晶胞参数a=13.991 Å b=11.3985 Å c 7.2081 Å。它在气相时和固相一样,有着C2对称性。[1]

制备

二苄基硫醚工业上利用氯化苄硫化钾的反应经蒸馏得到。[2] 它也可通过二苄基二硫化物和膦类试剂的脱硫反应得到。[3]

参考文献

  1. ^ Hansson, Christian. Dibenzyl sulfide at 150 K. Acta Crystallographica Section E Structure Reports Online. 19 May 2006, 62 (6): o2377–o2379. doi:10.1107/S1600536806017491. 
  2. ^ Lewis, R.J. Sr (编). Hawley's Condensed Chemical Dictionary 12. New York, NY: Van Nostrand Rheinhold Co. 1993: 137. 
  3. ^ Harpp, David N.; Smith, Roger A. Sulfide Synthesis: Benzyl Sulfide. Org. Synth. 1978, 58: 138. doi:10.15227/orgsyn.058.0138. 
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二苄基硫醚
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