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Kloroformiata acido

Kloroformiata acido

kloroformiata acido

Plata kemia strukturo de la
Kloroformiata acido

kloroformiata acido

Tridimensia kemia strukturo de la
Kloroformiata acido

Alternativa(j) nomo(j)

Klorokarbonata acido
Hidrogena kloroformiato
Kloroformiato de hidrogeno
Karbonoklorida acido

CHClO₂

CAS-numero-kodo

ChemSpider kodo

Fizikaj proprecoj

80.467 g·mol⁻¹

1.576g cm⁻³

Refrakta indico

{\displaystyle n_{761}^{20))

1,4267

GHS etikedigo de kemiaĵoj

GHS Damaĝo-piktogramo

05 – Koroda substanco

06 – Venena substanco

GHS Signalvorto

Damaĝo

GHS Deklaroj pri damaĝoj

H314, H330, H331

GHS Deklaroj pri antaŭgardoj

P260, P261, P264, P271, P280, P284, P301+330+331, P303+361+353, P304+340, P305+351+338, P310, P311, P320, P321, P363, P403+233, P405, P501

Escepte kiam indikitaj, datumoj estas prezentataj laŭ iliaj normaj kondiĉoj pri temperaturo kaj premo
(25 °C kaj 100 kPa)

Kloroformiata acido estas malstabila klorokomponaĵo^[1], kies molekulo estas derivata el la formiata acido, kie unu hidrogenatomo estas anstataŭata de unu kloratomo. Kvankam tiu substanco preskaŭ neekzistas en akva solvaĵo, ĝiaj esteroj (tiaj kiaj metila kloroformiato kaj etila kloroformiato) estas pli stabilaj.

Ĝenerale, kloroformiatoj plenumas gravajn rolojn en organika kemio. Ili uzatas en la produktado de anhidridoj de karboksilataj acidoj necesaj en la sintezo de peptidoj. Kiel aliaj halokarbonidoj, ili estas potence danĝeraj alkiligagentoj.

Sintezoj

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Sintezo 1

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Preparado per interagado de formiata acido kaj kloro:

+ ${\mathsf ((\xrightarrow[{}]{))\,))$ +

Sintezo 2

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Preparado ekde la formiata acido kaj fosfora triklorido:

3+ ${\mathsf ((\xrightarrow[{}]{))\,))$ 3+

Sintezo 3

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Preparado per traktado de formiata acido kaj fosfora pentaklorido:

+ ${\mathsf ((\xrightarrow[{}]{))\,))$ ++

Sintezo 4

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Preparado inter formiata acido kaj nitrozila klorido:

+ ${\mathsf ((\xrightarrow[{}]{))\,))$ +

Sintezo 5

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Preparado per interagado de formiata acido kaj tionila klorido:

+ ${\mathsf ((\xrightarrow[{}]{))\,))$ ++

Sintezo 6

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Preparado per hidratigo de la fosgeno:

+ ${\mathsf ((\xrightarrow[{}]{))\,))$ +

Reakcioj

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Reakcio 1

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Hidratigo de la "kloroformiata acido":

+ ${\mathsf ((\xrightarrow[{}]{))\,))$ +

Reakcio 2

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Sapigo de la "kloroformiata acido":

+ ${\mathsf ((\xrightarrow[{}]{))\,))$ +

Reakcio 3

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Alkohola konvertado de la "kloroformiata acido":

+ ${\mathsf ((\xrightarrow[{}]{))\,))$ +

Reakcio 4

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Estera konvertado de la "kloroformiata acido":

+ ${\mathsf ((\xrightarrow[{}]{))\,))$ +

Reakcio 5

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Reakcio kun amoniako:

+ ${\mathsf ((\xrightarrow[{}]{))\,))$ +

Reakcio 6

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Reakcio kun jodida acido:

+ ${\mathsf ((\xrightarrow[{}]{))\,))$ +

Reakcio 7

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Varma malkomponado de la "kloroformiata acido":

${\mathsf ((\xrightarrow[{}]{))\,))$ +

Literaturo

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Pesticide Chemistry, G. Matolcsy, M. Nádasy, V. Andriska
Comprehensive Organic Functional Group Transformations, Volume 6, Alan R. Katritzky, Thomas L. Gilchrist, Otto Meth-Cohn, Charles Wayne Rees
Houben-Weyl Methods of Organic Chemistry Vol. E 23o, 4th Edition Supplement ..., Houben-Weyl, Karl-Heinz Büchel, Jürgen Falbe, Herrmann Hagemann, Michael Hanack
Aliphatic Organic Chemistry, Amit Arora
Shock Waves @ Marseille II: Physico-Chemical Processes and Nonequilibrium ..., Raymond Brun,Lucien Z. Dumitrescu
Competition Science Vision

Vidu ankaŭ

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Referencoj

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↑ Chemistry Division Annual Progress Report for Period Ending ...

Kategorio Kloroformiata acido en la Vikimedia Komunejo (Multrimedaj datumoj)

Kategorioj

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