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钒酸钕

钒酸钕

识别
CAS号 13721-46-5(无水)  checkY
86880-89-9(水合物)  checkY
PubChem 21909438
SMILES
 
  • [O-][V](=O)([O-])[O-].[Nd+3]
性质
化学式 NdVO4
摩尔质量 259.181 g·mol⁻¹
外观 浅蓝色晶体(水合物)
密度 4,979 g/cm3
溶解性 难溶
结构
晶格常数 a = 0.736 nm, b = 0.736 nm, c = 0.6471 nm[1]
相关物质
其他阴离子 铌酸钕
钽酸钕
其他阳离子 钒酸钇
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

钒酸钕是一种无机化合物,化学式为NdVO4。它可由硝酸钕偏钒酸铵柠檬酸在溶液中混合,再分别于400 °C和550 °C加热得到。[2]氧化钕五氧化二钒在高温反应,也能得到钒酸钕。[3]它和氨气反应,可以得到NdVO2N。[4]

参考文献

[编辑]
  1. ^ Handbook… (Pierre Villars, Karin Cenzual, Roman Gladyshevskii; Walter de Gruyter GmbH & Co KG, 24 thg 7, 2017 - 1970 trang). [2021-01-20].
  2. ^ Chak-Tong Au, Wei-De Zhang. Oxidative dehydrogenation of propane over rare-earth orthovanadates. Journal of the Chemical Society, Faraday Transactions. 1997, 93 (6): 1195–1204 [2022-05-09]. doi:10.1039/a607565g. 
  3. ^ A. S. Lyadov, V. V. Kurilkin. Reduction specifics of rare-earth orthovanadates (REE = La, Nd, Sm, Dy, Ho, Er, Tm, Yb, and Lu). Russian Journal of Inorganic Chemistry. 2016-01, 61 (1): 86–92 [2022-05-09]. ISSN 0036-0236. doi:10.1134/S0036023616010150 (英语). 
  4. ^ Judith Oró-Solé, Lucy Clark, Nitesh Kumar, William Bonin, A. Sundaresan, J. Paul Attfield, C. N. R. Rao, Amparo Fuertes. Synthesis, anion order and magnetic properties of RVO3−xNx perovskites (R = La, Pr, Nd; 0 ≤ x ≤ 1). Journal of Materials Chemistry C. 2014, 2 (12): 2212 [2022-05-09]. ISSN 2050-7526. doi:10.1039/c3tc32362e (英语). 
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钒酸钕
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