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金属有机框架材料

一个MOF晶体的扫描电子显微镜图像

金属有机框架材料金属有机骨架材料(英语:Metal Organic Frameworks,缩写:MOF)是新材料在金属有机材料(MOM)中的一个重要分类。MOF是新无机有机材料中研究最热门的一个领域,因为他们将两门经常被分开的化学学科无机化学有机化学结合了起来。[1]MOF由有机配体配位的金属原子原子簇构成一维、二维或三维的结构。MOF可用于气体吸附、气体储存、气体分离、催化剂等领域。

常见的金属有机框架材料

分子式 连接配体 MOF名称 注释
Cu3(C9H3O6)2(H2O)3 均苯三甲酸 HKUST-1
Cr(OH){O2CC6H4CO2} 对苯二甲酸 MIL-53(Cr) 其它三价金属的类似物,如MIL-53(Al)是已知的[2]
Zn4O(O2CC6H4CO2)3 对苯二甲酸 MOF-5
Cu2(H2O)2(adip)·2DMF 5,5'-(9,10-蒽二基)二(1,3-苯二甲酸) PCN-14

参见

参考文献

  1. ^ Adeel H. Chughtai, et al. Metal–organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations. Chem. Soc. Rev., 2015, 44, 6804. doi:10.1039/c4cs00395k
  2. ^ Franck Millange, Richard I. Walton. MIL-53 and its Isoreticular Analogues: a Review of the Chemistry and Structure of a Prototypical Flexible Metal-Organic Framework. Israel Journal of Chemistry. 2018-10, 58 (9-10): 1019–1035 [2022-11-19]. doi:10.1002/ijch.201800084. (原始内容存档于2022-10-20) (英语). 

参见

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金属有机框架材料
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