苯甲酸铀酰
| 苯甲酸铀酰 | |
|---|---|
| 识别 | |
| CAS号 | 532-60-5  25935-09-5
|
| 性质 | |
| 化学式 | C14H10O6U |
| 摩尔质量 | 512.25 g·mol−1 |
| 外观 | 黄色晶体[1] |
| 密度 | 2.44 g·cm−3[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
苯甲酸铀酰是一种化合物，化学式为UO2(C6H5COO)2。它可由乙酸铀酰二水合物和苯甲酸按化学计量比反应得到，[2]或由氢氧化铀酰和苯甲酸在封管中于400 K反应制得。[1]它可以和DMSO反应，得到UO2(C6H5COO)2(DMSO)2。[3]
参考文献
[编辑]- ^ 1.0 1.1 1.2 A. Cousson, J. Proust, M. Pagès, F. Robert, E. N. Rizkalla. Structure of dibenzoatodioxouranium(VI). Acta Crystallographica Section C Crystal Structure Communications. 1990-12-15, 46 (12): 2316–2318 [2023-02-27]. doi:10.1107/S0108270190002761. （原始内容存档于2023-02-27）.
- ^ M.A Denecke, T Reich, M Bubner, S Pompe, K.H Heise, H Nitsche, P.G Allen, J.J Bucher, N.M Edelstein, D.K Shuh. Determination of structural parameters of uranyl ions complexed with organic acids using EXAFS. Journal of Alloys and Compounds. 1998-06,. 271-273: 123–127 [2023-02-27]. doi:10.1016/S0925-8388(98)00038-3 （英语）.
- ^ Shchelokov, R.N.; Mikhajlov, Yu.N.; Orlova, I.M.; Sergeev, A.V.; Ashurov, Z.R.; Tashev, M.T.; Parpiev, N.A. Synthesis and crystal structure of bis-dimethylsulfoxide-bis-benzoatouranyl, [UO2(C6H5COO)2(OS(CH3)2)2]. Koordinatsionnaya Khimiya. 1985. 11 (5): 706-711.
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