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简并能级

简并能级(英語:Degenerate energy level)在物理学中,简并是指被当作同一较粗糙物理状态的两个或多个不同的较精细物理状态。[1]:p. 48

例如:

简并在量子力学和统计物理中的意义不同,在统计物理中,简并是指量子效应明显的体系。[2]:p. 52[3]

含有简并电子基态的非直线型分子都会产生姜-泰勒效应,而发生构型扭曲,例如六水合铜离子[Cu(OH2)6]2+的表象平面正方结构。

参考资料

[编辑]
  1. ^ Merzbacher, Eugen. Quantum Mechanics 3rd. New York: John Wiley. 1998. ISBN 0471887021. 
  2. ^ Levine, Ira N. Quantum Chemistry 4th. Prentice Hall. 1991: 52. ISBN 0-205-12770-3. 
  3. ^ Messiah, Albert. Quantum mechanics 3rd. Amsterdam, NLD: North-Holland. 1967: 98–106. ISBN 0471887021. 
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简并能级
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