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硝酸镧

硝酸镧
识别
CAS号 10099-59-9(无水)  checkY
15878-73-6(四水)  checkY
10277-43-7(六水)  checkY
性质
化学式 La(NO3)3
摩尔质量 324.926(无水)
396.99(四水)
433.022(六水) g·mol⁻¹
外观 白色易潮解的晶体
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

硝酸镧是一种无机化合物,化学式为La(NO3)3

制备

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硝酸镧可以将氧化镧氢氧化镧碳酸镧溶于硝酸得到:[1]

La2O3 + 6 HNO3 → 2 La(NO3)3 + 3 H2O
La(OH)3 + 3 HNO3 → La(NO3)3 + 3 H2O

所得溶液经过小心蒸发可以得到水合硝酸镧,其中六水合物最常见。将六水合物继续小心加热,可以得到无水物。

化学性质

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硝酸镧可以和一些金属盐形成复盐,如Cu、Mg、Mn等。

硝酸镧的水合物受热先失水,然后分解产生LaONO3, 继续加热得到氧化镧

参考资料

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  1. ^ 《无机化学丛书》.第七卷 钪 稀土元素. P233. 11.硝酸盐及其复盐
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硝酸镧
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