溴化四乙酸二锝
| 溴化四乙酸二锝 | |
|---|---|
| 识别 | |
| CAS号 | 83971-80-6 
|
| 性质 | |
| 化学式 | C8H12BrO8Tc2 |
| 摩尔质量 | 510.08 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
溴化四乙酸二锝是一种无机化合物，化学式为Tc2(OAc)4Br，其中OAc−为乙酸根。它可由M2Tc2Br6·2H2O（M=NH4, K）和乙酸在230~250 °C于50 atm氩气中反应得到。[1]它是单斜晶系晶体，空间群C2/m，其结构含[Tc2(OAc)4]+和Br−，其中Br−为桥联配体，连接两个锝原子。[2]
参考文献
[编辑]- ^ Kryuchkov, S. V.; Kuzina, A. F.; Spitsyn, V. I. New technetium halide clusters. Doklady Akademii Nauk SSSR. 1982, 266 (1): 127–130. ISSN 0002-3264.
- ^ Koz'min, P. A.; Larina, T. B.; Surazhskaya, M. D. Atomic and molecular structure of bromotetraacetatoditechnetium (Tc2(CH3COO)4Br). Technetium-technetium bondmultiplicity. Koordinatsionnaya Khimiya. 1983, 9 (8): 1114–1117. ISSN 0132-344X.
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