氧化膦
氧化膦 | |
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识别 | |
CAS号 | 13840-40-9 |
PubChem | 57448882 |
SMILES |
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性质 | |
化学式 | H3OP |
摩尔质量 | 50 g·mol−1 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
氧化膦是一种无机化合物,化学式为H3PO,它只在稀释的气相中稳定,而在液相或固相时不稳定。[1]它作为磷化氢和氧气反应的产物通过质谱检测得到。[2]它也是一氧化氮和磷化氢在室温反应,生成PxHy固体的中间体。[3]
参考文献
[编辑]- ^ Greenwood, Norman Neill; Earnshaw, Alan. Chemistry of the elements. 2016. ISBN 978-0-7506-3365-9. OCLC 1040112384 (英语).
- ^ Hamilton, Peter A.; Murrells, Timothy P. Kinetics and mechanism of the reactions of PH3 with O(3P) and N(4S) atoms. J. Chem. Soc., Faraday Trans. 1985, 2 (81): 1531–1541. doi:10.1039/F29858101531.
- ^ Zhao, Yi-Lei; Flora, Jason W.; David Thweatt, William; Garrison, Stephen L.; Gonzalez, Carlos; Houk, K. N.; Marquez, Manuel. Phosphine Polymerization by Nitric Oxide: Experimental Characterization and Theoretical Predictions of Mechanism. Inorg. Chem. 2009, 48 (3): 1223–1231. PMID 19102679. doi:10.1021/ic801917a.
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