氢化铝铷
| 氢化铝铷 | |
|---|---|
| 别名 | 四氢合铝(III)酸铷 |
| 性质 | |
| 化学式 | RbAlH4 |
| 外观 | 固体 |
| 相关物质 | |
| 其他阴离子 | 硼氢化铷 |
| 其他阳离子 | 氢化铝铯 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
氢化铝铷是一种无机化合物，化学式为RbAlH4。它可由氯化铷或氟化铷与氢化铝钠或氢化铝锂通过球磨法得到，或铷、铝在5% TiCl3存在下于氢气（20 MPa）中球磨得到。[1]经ab-initio计算，空间群Pmma的α-RbAlH4会在32 kbar转化为I41/a，在68 kbar转化为Cmc21空间群。[2]
参考文献
[编辑]- ^ Claudia Weidenthaler, Michael Felderhoff, Thomas Bernert, Magnus Sørby, Bjørn Hauback, Daniel Krech. Synthesis, Crystal Structure Analysis and Decomposition of RbAlH4. Crystals. 2018-02-22, 8 (2): 103 [2023-01-05]. ISSN 2073-4352. doi:10.3390/cryst8020103. （原始内容存档于2023-01-05） （英语）.
- ^ Suárez-Alcántara, Tena-Garcia, Guerrero-Ortiz. Alanates, a Comprehensive Review. Materials. 2019-08-25, 12 (17): 2724 [2023-01-05]. ISSN 1996-1944. PMC 6747775
. PMID 31450714. doi:10.3390/ma12172724. （原始内容存档于2023-01-05） （英语）.
拓展阅读
[编辑]
- S. I. Bakum, U. Mirsaidov, T. N. Dymova. Solubility diagram of system: RbAlH4-diethylene glycol dimethyl ether. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1972-11, 21 (11): 2539–2540 [2023-01-05]. ISSN 0568-5230. doi:10.1007/BF00850117 （英语）.
- P. Ravindran, P. Vajeeston, R. Vidya, H. Fjellvåg, A. Kjekshus. Modeling of hydrogen storage materials by density-functional calculations. Journal of Power Sources. 2006-09, 159 (1): 88–99 [2023-01-05]. doi:10.1016/j.jpowsour.2006.04.060. （原始内容存档于2023-05-22） （英语）.
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