亚硫酸铯
| 亚硫酸铯 | ||
|---|---|---|
| ||
| 英文名 | Caesium sulfite | |
| 识别 | ||
| CAS号 | 18832-76-3 
| |
| 性质 | ||
| 化学式 | Cs2O3S | |
| 摩尔质量 | 345.87 g·mol−1 | |
| 外观 | 白色晶体[1] | |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | ||
亚硫酸铯是一种无机化合物，化学式为Cs2SO3，易溶于水，微溶于乙醇。[2]它和硝普铯反应，可以得到暗红色的Cs4Fe(CN)5NOSO3晶体。[3]它在二氧化硫中是一种碱，可以和氯化亚砜发生中和反应：[4]
- Cs2SO3 + SOCl2 → 2 CsCl + 2 SO2
参考文献
[编辑]- ^ Chabrie, Camille. Caesium compounds. Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1901. 133: 295-297. CODEN: COREAF.
- ^ Comey, A.M. A Dictionary of chemical solubilities. Macmillan Company. 1921: 1040 [2021-10-22]. （原始内容存档于2021-10-30）.
- ^ Fogg, Arnold G.; Norbury, Allan H.; Moser, Wolfgang. Boedeker reaction. IV. Cesium sulfitonitroprusside. Journal of Inorganic and Nuclear Chemistry, 1966. 28 (11): 2753-2755. ISSN: 0022-1902.
- ^ et, S.P. Advanced Inorganic Chemistry - Volume II. Advanced Inorganic Chemistry. S. Chand Limited. 2000: 601 [2021-10-22]. ISBN 978-81-219-1787-2. （原始内容存档于2021-10-22）.
拓展阅读
[编辑]
- Christian Archer, Jean Durand, Louis Cot, Jean Louis Galigne. Sur quelques sulfites de cations monovalents; étude structurale de LiCsSO 3 •2H 2 O. Canadian Journal of Chemistry. 1979-04-15, 57 (8): 899–903 [2021-10-22]. ISSN 0008-4042. doi:10.1139/v79-148 （英语）.
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