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五氟氯化铀

五氟氯化铀
英文名 Uranium chloride pentafluoride
别名 五氟一氯化铀
识别
CAS号 77849-15-1  checkY
SMILES
 
  • F[U](F)(F)(F)(F)Cl
性质
化学式 ClF5U
摩尔质量 368.47 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

五氟氯化铀是一种无机化合物,化学式为UClF5。它可由六氟化铀氯化氢(或三甲基氯硅烷[1])反应制得。如果以三氯化硼三氯化铝四氯化钛为氯化剂,则会产生六氯化铀[2]它是一种氧化剂,和二氧化氮在低温下反应,生成五氟化铀硝酰氯;和四氟乙烯反应,可以得到CF2XCF2Cl(X=F或Cl),自身被还原为五氟化铀或四氟化铀[3]

参考文献

[编辑]
  1. ^ Anthony J. Downs, Christopher J. Gardner. Formation and characterization of uranium( VI ) chloride fluorides,UFnCl 6–n (n= 1–5). J. Chem. Soc., Dalton Trans. 1984, (10): 2127–2132 [2020-10-28]. ISSN 0300-9246. doi:10.1039/DT9840002127 (英语). 
  2. ^ Willard H. Beattie, William B. Maier. Synthesis and characterization of uranium (VI) chloride flourides. Polyhedron. 1983-01, 2 (12): 1371–1378 [2020-10-28]. doi:10.1016/S0277-5387(00)84401-0. (原始内容存档于2018-07-03) (英语). 
  3. ^ Anthony J. Downs, Christopher J. Gardner. Some reactions of uranium chloride pentafluoride. Journal of the Chemical Society, Dalton Transactions. 1986, (6): 1289 [2020-10-28]. ISSN 0300-9246. doi:10.1039/dt9860001289 (英语). 
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五氟氯化铀
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