二氯化二(1,3,5-三氮杂-7-磷杂金刚烷)合铂
| 二氯化二(1,3,5-三氮杂-7-磷杂金刚烷)合铂 | |
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| 识别 | |
| CAS号 | 194346-40-2 
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| 性质 | |
| 化学式 | H24Cl2N6P2Pt |
| 摩尔质量 | 436.17 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
二氯化二(1,3,5-三氮杂-7-磷杂金刚烷)合铂是一种配位化合物，化学式为PtCl2P2C12H24N6。它可由四氯合铂(II)酸钾和1,3,5-三氮杂-7-磷杂金刚烷（PTA）在乙醇中反应制得，[1]，或通过PtCl2(COD)（COD=1,5-环辛二烯）和PTA反应得到。[2]它在0.1 mol/L的盐酸溶液中可以结晶出无色的cis-[PtCl2(PTAH)2]Cl2晶体。[1]它的配位氯可以被含硫配体取代。[3]
参考文献
[编辑]- ^ 1.0 1.1 Donald J. Darensbourg; et al. Water-Soluble Organometallic Compounds. 6.1 Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals. Inorg. Chem. 1997, 36, 19, 4218–4226. doi:10.1021/ic970238x.
- ^ Don A. Krogstad; et al. Intramolecular hydroamination of alkynylamines in aqueous media catalyzed by platinum(II) 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. Inorganic Chemistry Communications, 2005. 8 (1): 65-69. doi:10.1016/j.inoche.2004.11.006.
- ^ Elena Guerrero; et al. trans-Thionate Derivatives of Pt(II) and Pd(II) with Water-Soluble Phosphane PTA and DAPTA Ligands: Antiproliferative Activity against Human Ovarian Cancer Cell Lines. Inorg. Chem. 2013, 52, 11, 6635–6647. doi:10.1021/ic4006746.
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