三氟乙酸锂
三氟乙酸锂 | |
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识别 | |
CAS号 | 2923-17-3 ![]() |
性质 | |
化学式 | C2F3LiO2 |
摩尔质量 | 119.96 g·mol−1 |
外观 | 白色固体 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
三氟乙酸锂是一种化合物,化学式为CF3COOLi,它可由三氟乙酸和碳酸锂反应得到[1],它在250 °C开始分解,产物是氟化锂和一些气态产物。[2]
它和三氟甲磺酸氧钒(IV)、2,2'-联吡啶反应,可以得到[Li2(VO)2(μ-CF3COO)6(bpy)2]。[3]
参考文献
[编辑]- ^ Christian Rüssel. A pyrolytic route to fluoride glasses. I. Preparation and thermal decomposition of metal trifluoroacetates. Journal of Non-Crystalline Solids. 1993-02, 152 (2-3): 161–166 [2021-10-20]. doi:10.1016/0022-3093(93)90246-T. (原始内容存档于2018-07-01) (英语).
- ^ R. Dallenbach, P. Tissot. Properties of molten alkali metal trifluoracetates: Part II. Thermal properties and kinetics of thermal decomposition. Journal of Thermal Analysis. 1981-04, 20 (2): 409–417 [2021-10-20]. ISSN 0022-5215. doi:10.1007/BF01912890 (英语).
- ^ Evgeniya S. Bazhina, Grigory G. Aleksandrov, Mikhail A. Kiskin, Nikolay N. Efimov, Elena A. Ugolkova, Alexander A. Korlyukov, Oleg M. Nikitin, Tatiana V. Magdesieva, Vadim V. Minin, Alexey A. Sidorov, Joel S. Miller, Igor L. Eremenko. Synthesis, crystal structure and spin exchange coupling in polynuclear carboxylates with {Li 2 (VO) 2 } metal core. Polyhedron. 2017-11, 137: 246–255 [2021-10-20]. doi:10.1016/j.poly.2017.08.005. (原始内容存档于2020-02-14) (英语).
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