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一硅化钙

一硅化钙
识别
CAS号 12013-55-7  checkY
PubChem 6336872
ChemSpider 4891865
SMILES
 
  • [Si]=[Ca]
UN编号 1405
EINECS 234-587-1
性质
化学式 CaSi
摩尔质量 68.164[1] g·mol⁻¹
密度 2.39 g/cm3[1]
熔点 1324 °C(1597 K)
结构
晶体结构 正交, oS8,
空间群 Cmcm, No. 63
晶格常数 a = 0.4545 nm, b = 1.0728 nm, c = 0.389 nm
危险性
GHS危险性符号
《全球化学品统一分类和标签制度》(简称“GHS”)中易燃物的标签图案
GHS提示词 Warning
H-术语 H261
P-术语 P231+232, P280, P370+378, P402+404, P501
主要危害 和水反应放出易燃气体
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

一硅化钙是一种无机化合物,化学式为CaSi,它可由在1000 °C以上反应得到:[2]

Ca + Si → CaSi

它是正交晶系晶体,空间群Cmcm。[3]

参考文献

[编辑]
  1. ^ 1.0 1.1 Haynes, William M. CRC handbook of chemistry and physics: a ready-reference book of chemical and physical data 92nd. Boca Raton, FL.: CRC Press英语CRC Press. 2011: 4.55. ISBN 978-1-4398-5511-9. OCLC 730008390 (英语). 
  2. ^ Brauer, Georg (1975) Handbuch der Präparativen Anorganischen Chemie. Stuttgart. Vol. 1. p. 933. ISBN 3-432-02328-6.
  3. ^ Rieger, W; Parthé, E. Alkaline earth silicides, germanides and stannides with CrB structure type. Acta Crystallographica. 1967, 22 (6): 919. doi:10.1107/S0365110X67001793. 
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一硅化钙
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