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锡酸盐.
锡酸盐是锡的含氧酸盐,有多个种类,可以锡或二氧化锡为原料来制备。它可用作半导体材料[1]或发光材料[2]。它在自然界中有多种矿物,如水镁锡矿等。[3]
锡酸盐的种类
锡酸盐主要有以下三种:
- 偏锡酸盐:符合MI2SnO3、MIISnO3元素计量比的化合物,其中一价金属的化合物可能含有聚阴离子,有时更适合写成混合氧化物的形式;
- 正锡酸盐(原锡酸盐):含有独立SnO4−
4单元的化合物,如K4SnO4;或具有尖晶石结构的锡化合物,如Mg2SnO4。
- 羟基锡酸盐:含有[Sn(OH)6]4−的化合物。
参考文献
- ^ "Preparation, characterization and structure of metal stannates: a new family of photocatalysts for organic pollutants degradation." Handbook of Photocatalysts (2010), pp. 493–510. Nova Science Publishers, Inc., Hauppauge, NY
- ^ 杨鹏辉, 余雪, 宋志国,等. 稀土掺杂的锡酸盐荧光材料光学性能的研究[C]// 战略性新兴产业的培育和发展——首届云南省科协学术年会论文集. 2011.
- ^ 魏明秀, 王凤阁, 殷成玉. 水镁锡矿在我国的发现. 科学通报, 1982, 27(4):230-233.
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