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硫代硫酸铵

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硫代硫酸铵
IUPAC名
Ammonium thiosulfate
识别
CAS号 7783-18-8  checkY
PubChem 6096946
ChemSpider 4807475
InChI
 
  • InChI=1S/2H3N.H2O3S2/c;;1-5(2,3)4/h2*1H3;(H2,1,2,3,4)
性质
化学式 (NH4)2S2O3
摩尔质量 148.20 g·mol⁻¹
外观 白色单斜结晶
密度 1.679
熔点 150℃(分解)
结构
晶体结构 单斜晶系
危险性
闪点 ?°C
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

硫代硫酸铵分子式为(NH4)2S2O3,是硫代硫酸盐的一种。

性质

[编辑]

一种有强烈吸湿性的白色斜方结晶,加热至150℃会分解成亚硫酸铵硫黄硫化氢。极易溶于水,不溶于,微溶于丙酮。在空气中不稳定,在氨气中稳定。

制法

[编辑]

碳酸氢铵二氧化硫和水作用产生亚硫酸铵,经过滤除去杂质后再与硫黄加热煮沸反应,再经过滤、蒸发、冷却结晶和离心分离,得到硫代硫酸铵成品。

用途

[编辑]

感光工业中用作照相定影剂,用于替代硫代硫酸钠,具有水洗时间短和银容易回收的优点,且较钠盐更易溶解卤化银的乳膜。在医药上用作杀菌剂、分析试剂。

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硫代硫酸铵
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