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十三烷二酸

十三烷二酸
IUPAC名
tridecanedioic acid
识别
CAS号 505-52-2  checkY
PubChem 10458
性质
化学式 C13H24O4
摩尔质量 244.33 g·mol−1
外观 白色固体
熔点 114 °C(387 K)
溶解性 0.0025 g/100 mL
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

十三烷二酸(英语:tridecanedioic acid,别名巴西基酸,英语:Brassylic acid)是一种有机化合物,化学式为(CH
2
)
11
(CO
2
H)
2
。它可由芥酸(13-二十二烯酸)的催化氧化制得。[1]它具有羧酸的通性,如在硫酸存在下和甲醇发生酯化反应,得到十三烷二酸二甲酯;[2]氯化亚砜回流反应,得到十三烷二酸二甲酰氯。[3]

参考文献

  1. ^ Renat Kadyrov, Dagmar Hackenberger. Oxidative Cleavage of Long Chain Olefins to Carboxylic Acids with Hydrogen Peroxide. Topics in Catalysis. 2014-11, 57 (17-20): 1366–1371 [2022-12-07]. ISSN 1022-5528. doi:10.1007/s11244-014-0304-6 (英语). 
  2. ^ Kenji Mori, Hiroyuki Nishio. Synthesis of sphingosine relatives, IX. Synthesis of (2S,3R,4E)-1-O-(β-D-glucopyranosyl)-N- [24-(linoleoyloxy)tetracosanoyl]-4-sphingenine. The structure proposed for the esterified cerebroside in the epidermis of guinea pigs. Liebigs Annalen der Chemie. 1991-03-12, 1991 (3): 253–257 [2022-12-07]. doi:10.1002/jlac.199119910143 (德语). 
  3. ^ Anna Zep, Kaja Sitkowska, Damian Pociecha, Ewa Gorecka. Photoresponsive helical nanofilaments of B 4 phase. J. Mater. Chem. C. 2014, 2 (13): 2323–2327 [2022-12-07]. ISSN 2050-7526. doi:10.1039/C3TC32325K (英语). 
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十三烷二酸
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