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二氰合金酸铕

二氰合金酸铕

英文名 europium(III) dicyanoaurate(I)
识别
CAS号 156220-29-0  checkY
性质
化学式 C6Au3EuN6
摩尔质量 898.97 g·mol−1
外观 浅黄色晶体[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二氰合金酸铕是一种配位化合物,化学式为Eu[Au(CN)2]3。它可由氰化亚金钾硝酸铕按化学计量比在水溶液中混合,缓慢蒸发溶液,结晶得到。[1]其三水合物的光谱得到了测定。[2]

参考文献

  1. ^ 1.0 1.1 Zerihun Assefa, George Shankle, Howard H. Patterson, Ross Reynolds. Photoluminescence studies of lanthanide ion complexes of gold and silver dicyanides: a new low-dimensional solid state class for nonradiative excited-state energy transfer. Inorganic Chemistry. 1994-05, 33 (10): 2187–2195 [2020-02-23]. ISSN 0020-1669. doi:10.1021/ic00088a021 (英语). 
  2. ^ Hartmut Yersin, Dietrich Trümbach, Johann Strasser, Howard H. Patterson, Zerihun Assefa. Tunable Radiationless Energy Transfer in Eu[Au(CN) 2 ] 3 ·3H 2 O by High Pressure. Inorganic Chemistry. 1998-06, 37 (13): 3209–3216 [2020-02-23]. ISSN 0020-1669. doi:10.1021/ic980252p (英语). 
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二氰合金酸铕
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