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丙酸铀酰

丙酸铀酰
别名 丙酸双氧铀
识别
CAS号 29054-14-6(无水)  checkY
30827-42-0(二水)  checkY
性质
化学式 C6H10O6U
摩尔质量 416.17 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

丙酸铀酰是一种六价铀的羧酸盐,化学式为UO2(C2H5COO)2。它可由三氧化铀丙酸反应得到。[1]它的热分解产物为八氧化三铀[1]它的二水合物和尿素反应,可以得到UO2(C2H5COO)2·2CO(NH2)2·H2O。[2]它和丙酸镁反应,可以得到Mg[UO2(C2H5COO)3]2·6H2O。[3]

参考文献

  1. ^ 1.0 1.1 R. M. Rojas, J. Bermudez, E. Criado. Thermal decomposition of uranyl propionate dihydrate. Journal of Thermal Analysis. 1971-09, 3 (3): 277–280 [2022-08-16]. ISSN 0022-5215. doi:10.1007/BF01912111 (英语). 
  2. ^ V. N. Serezhkin, M. S. Grigor’ev, A. R. Abdul’myanov, L. B. Serezhkina. Structure and some properties of UO2(C2H5COO)2 · nQ · mH2O (Q is carbamide or ethylenecarbamide). Russian Journal of Inorganic Chemistry. 2016-01, 61 (1): 24–32 [2022-08-16]. ISSN 0036-0236. doi:10.1134/S0036023616010228 (英语). 
  3. ^ Viktor N. Serezhkin, Mikhail S. Grigoriev, Aleksey R. Abdulmyanov, Aleksandr M. Fedoseev, Anton V. Savchenkov, Larisa B. Serezhkina. Synthesis and X-ray Crystallography of [Mg(H 2 O) 6 ][AnO 2 (C 2 H 5 COO) 3 ] 2 (An = U, Np, or Pu). Inorganic Chemistry. 2016-08-01, 55 (15): 7688–7693 [2022-08-16]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.6b01154. (原始内容存档于2022-03-05) (英语). 

拓展阅读

  • Alikhanova, Z. M.; Zolin, V. F.; Fisher, P. S.; Ellert, G. V. Luminescence spectra and structure of uranyl propionates(俄文). Zhurnal Neorganicheskoi Khimii, 1970. 15 (11): 3119-3123.

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丙酸铀酰
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