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三茂钇

三茂钇
识别
CAS号 1294-07-1  checkY
SMILES
 
  • c1ccc[cH-]1.c2ccc[cH-]2.c3ccc[cH-]3.[Y+3]
性质
化学式 C15H15Y
摩尔质量 284.19 g·mol−1
熔点 295 °C(568 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

三茂钇是一种有机钇化合物,化学式为Y(C5H5)3。它是浅黄色的晶体,可由无水三氯化钇环戊二烯基钠四氢呋喃中反应得到。它遇水分解,生成环戊二烯氢氧化钇[1]其热稳定性介于二茂铁和其它3d过渡金属的三茂配合物之间。[2]

参考文献

  1. ^ 1.0 1.1 G. Wilkinson, J. M. Birmingham. CYCLOPENTADIENYL COMPOUNDS OF Sc, Y, La, Ce AND SOME LANTHANIDE ELEMENTS. Journal of the American Chemical Society. 1954-12, 76 (23): 6210–6210 [2020-12-09]. ISSN 0002-7863. doi:10.1021/ja01652a114. (原始内容存档于2021-07-16) (英语). 
  2. ^ Borisov, G. K.; Kuz'michev, A. I.; Ryzhikova, N. N.; Sinev, V. N. Thermolysis of cyclopentadienyl derivatives of rare earths. Zhurnal Obshchei Khimii, 1988. 58 (1): 71-76. ISSN: 0044-460X.
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三茂钇
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