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三氟甲磺酸亚硝酰

三氟甲磺酸亚硝酰
识别
CAS号 51637-52-6  checkY
SMILES
 
  • [N+]=O.O=S(=O)([O-])C(F)(F)F
性质
化学式 CF3NO4S
摩尔质量 179.08 g·mol−1
外观 无色吸湿性固体[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

三氟甲磺酸亚硝酰是一种无机化合物,化学式为NOCF3SO3,它可由三氟甲磺酸硝酰四氧化二氮反应得到。[2]它和NSAsF6二氧化硫中反应,可以得到NSCF3SO3[3]它和二乙基二硒或二乙基二碲在乙腈中反应,可以得到[EtE]4(CF3SO3)2(E=Se, Te)。[4]

参考文献

[编辑]
  1. ^ Fernandez, L. E.; Ben Altabef, A.; Varetti, E. L. The vibrational spectra of nitrosyl trifluoromethanesulfonate, NOCF3SO3. Asian Journal of Spectroscopy, 1998. 2 (4): 173-178. CODEN AJOSFO.
  2. ^ Schmeisser, Martin; Sartori, Peter; Lippsmeier, Bernd. Preparation of iodine tris(trifluoromethanesulfonate), nitryl, nitrosyl trifluoromethanesulfonate. III. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, Biochemie, Biophysik, Biologie. 1973, 28 (9-10): 573–574. ISSN 0044-3174 (德语). 
  3. ^ Mews, Ruediger. The thionitrosyl(1+) ion as a synthesis reagent. Angewandte Chemie. 1976, 88 (22): 757–758. ISSN 0044-8249 (德语). 
  4. ^ Mueller, Birgit; Poleschner, Helmut; Seppelt, Konrad. Dialkyl dichalcogen cations. Dalton Transactions (Royal Society of Chemistry (RSC)). 2008, (33): 4424. ISSN 1477-9226. doi:10.1039/b802259n. 
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三氟甲磺酸亚硝酰
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