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Dosya:Sbs block copolymer.jpg

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Açıklama
English: TEM micrograph using osmium tetroxide to preferentially stain the polybutadiene matrix.

From the thermoplastic elastomers article:

"Block copolymers are interesting because they can "microphase separate" to form periodic nanostructures, as in the styrene-butadiene-styrene block copolymer shown at right. The polymer is known as Kraton and is used for shoe soles and adhesives. Owing to the microfine structure, the transmission electron microscope or TEM was needed to examine the structure. The butadiene matrix was stained with osmium tetroxide to provide contrast in the image. The material was made by living polymerization so that the blocks are almost monodisperse, so helping to create a very regular microstructure. The molecular weight of the polystyrene blocks in the main picture is 102,000; the inset picture has a molecular weight of 91,000, producing slightly smaller domains. The spacing between domains has been confirmed by small-angle X-ray scattering, a technique which gives information about microstructure. Since most polymers are incompatible with one another, forming a block polymer will usually result in phase separation, and the principle has been widely exploited since the introduction of the SBS block polymers, especially where one of the block is highly crystalline. One exception to the rule of incompatibility is the material Noryl, where polystyrene and polyphenylene oxide or PPO form a continuous blend with one another."

Tarih
Kaynak Own work by the original uploader
Yazar Peter R Lewis
Diğer sürümler Also published in Polymer, 13, 22 (1972).

Lisanslama

Public domain Bu iş yazarı Peterlewis at İngilizce Vikipedi tarafından kamu malı olarak yayınlanmıştır. Bu dünya çapında geçerlidir.
Bazı ülkelerde bu yasal olarak mümkün olmayabilir; öyleyse:
Peterlewis, bu işi herhangi bir amaç için, herhangi bir şart olmaksızın, yasalarca gerekli olmadıkça, herkesin kullanmasına izin veriyor.

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  • 2008-02-29 09:17 Peterlewis 1018×717× (263502 bytes) TEM micrograph taken by author in 1970

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