Silimanit je jedan od tri alumosilikatna polimorfa - druga dva su andaluzit i kijanit i najrjeđi je među njima. Čest varijetet silimanita poznat je kao fibrolit, a nosi to ime zato što se pojavljuje kao snop međusobno sraslih vlakana koja se vide i pod malim povećanjima, pa čak i golim okom. I vlaknaste i forme običnih kristala silimanita česte su u metamorfoziranim sedimentnim stijenama.
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