In inorganic chemistry, titanyl refers to the functional group TiIVO, sometimes written TiO2+. The term titanyl is used loosely to describe many titanium(IV) oxide compounds and complexes. For example, titanyl sulfate and potassium titanyl phosphate contain TiIVO centers with the connectivity O-Ti-O-Ti. In heterogeneous catalysis, titanyl refers to a terminal oxo ligand on a surface titanium(IV) center.[2] There are a few molecular titanyl complexes where the oxo ligand is terminal, not bridging. In these cases the titanyl group is described as having a triple bond, i.e., Ti≡O.
^Axel Bodner; Peter Jeske; Thomas Weyhermueller; Karl Wieghardt; Erich Dubler; Helmut Schmalle; Bernhard Nuber (1992). "{Mono- and Dinuclear Titanium(III)/Titanium(IV) Complexes with 1,4,7-Trimethyl-1,4,7-triazacyclononane (L). Crystal Structures of a Compositionally Disordered Green and a Blue Form of [LTiCl3]. Structures of [LTi(O)(NCS)2], [LTi(OCH3)Br2](ClO4), and [L2Ti2(O)2F2(mu-F)](PF6)". Inorganic Chemistry. 31: 3737–3748. doi:10.1021/ic00044a015.
^John Meurig Thomas; Gopinathan Sankar (2001). "The Role of Synchrotron-Based Studies in the Elucidation and Design of Active Sites in Titanium−Silica Epoxidation Catalysts". Accounts of Chemical Research. 34: 571–581. doi:10.1021/ar010003w.
This browser is not supported by Wikiwand :( Wikiwand requires a browser with modern capabilities in order to provide you with the best reading experience. Please download and use one of the following browsers:
Your input will affect cover photo selection, along with input from other users.
X
Get ready for Wikiwand 2.0 🎉! the new version arrives on September 1st! Don't want to wait?
Oh no, there's been an error
Please help us solve this error by emailing us at support@wikiwand.com
Let us know what you've done that caused this error, what browser you're using, and whether you have any special extensions/add-ons installed.
Thank you!