Thiosulfuric acid
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| Names | |
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| IUPAC name
Sulfurothioic O-acid[3]
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| Systematic IUPAC name
Dihydroxidooxidosulfidosulfur[3] | |
| Other names
Thiosulfuric acid
Sulfurothioic O,O-acid[2] | |
| Identifiers | |
3D model (JSmol)
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| ChEBI | |
| ChemSpider | |
PubChem CID
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| UNII | |
CompTox Dashboard (EPA)
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| Properties[1][5] | |
| H2S2O3 | |
| Molar mass | 114.13 g·mol−1 |
| Melting point | decomposes below 0 °C |
| decomposes | |
| Acidity (pKa) | |
| Conjugate base | Thiosulfate |
| Related compounds | |
Other cations
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Thiosulfuric acid is the inorganic compound with the formula H2S2O3. It has attracted academic interest as a simple, easily accessed compound that is labile. It has few practical uses.
Preparation and degradation
The acid cannot be made by acidifying aqueous thiosulfate salt solutions as the acid readily decomposes in water. The decomposition products can include sulfur, sulfur dioxide, hydrogen sulfide, polysulfanes, sulfuric acid and polythionates, depending on the reaction conditions.[6] Anhydrous methods of producing the acid were developed by Max Schmidt:[6][7]
- H2S + SO3 → H2S2O3
- Na2S2O3 + 2 HCl → 2 NaCl + H2S2O3
- HSO3Cl + H2S → HCl + H2S2O3
The anhydrous acid also decomposes above −5 °C:[6]
- H2S2O3 → H2S + SO3
Structure
The isomer (O=)2S(−OH)(−SH) is more stable than the isomer (O=)(S=)S(−OH)2 as established by Hartree–Fock/ab initio calculations with a 6-311 G** basis set and MP2 to MP4 refinements.[8][clarification needed] The theoretically predicted structure conforms with the double bond rule.
An isomer of thiosulfuric acid is the adduct of hydrogen sulfide and sulfur trioxide, H2S·SO3, which can also be prepared at low temperature. It is a white crystalline solid.[6]
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