Silver tungstate
| Names | |
|---|---|
| IUPAC name
Disilver;dioxido(dioxo)tungsten
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.033.357 |
| EC Number |
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PubChem CID
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| Properties | |
| Ag2WO4 | |
| Molar mass | 463.57 g mol−1 |
| Hazards | |
| GHS labelling:[1] | |
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| Warning | |
| H315, H319, H335 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Silver tungstate is an inorganic tungstate with the chemical formula Ag2WO4. It has been applied in various fields such as photoluminescence, antibacterial action, ozone gas sensors and humidity sensors.[2][3] It is also used in the electronic and chemical industries, and also used in proteomics research.[4]
Phases
[edit]Silver tungstate occurs in three polymorphic phases: orthorhombic (α), hexagonal (β) and cubic (γ).[2] α-silver tungstate is thermodynamically stable, while β- and γ-silver tungstate are metastable.[5]
Synthesis
[edit]Silver tungstate is synthesised through the following reaction between silver nitrate and sodium tungstate, producing sodium nitrate as a byproduct:[2]
References
[edit]- ^ "C&L Inventory". echa.europa.eu.
- ^ a b c Sreedevi, A.; Priyanka, K. P.; Babitha, K. K.; Aloysius Sabu, N.; Anu, T. S.; Varghese, T. (2015-09-01). "Chemical synthesis, structural characterization and optical properties of nanophase α-Ag2WO4". Indian Journal of Physics. 89 (9): 889–897. Bibcode:2015InJPh..89..889S. doi:10.1007/s12648-015-0664-1. ISSN 0974-9845. S2CID 122042870.
- ^ De Santana, Yuri V. B.; Gomes, José Ernane Cardoso; Matos, Leandro; Cruvinel, Guilherme Henrique; Perrin, André; Perrin, Christiane; Andrès, Juan; Varela, José A.; Longo, Elson (2014-01-01). "Silver Molybdate and Silver Tungstate Nanocomposites with Enhanced Photoluminescence". Nanomaterials and Nanotechnology. 4: 22. doi:10.5772/58923. hdl:10234/121786. ISSN 1847-9804. S2CID 7415517.
- ^ "13465-93-5 - Silver tungsten oxide, 99% (metals basis) - Silver tungstate - 39661 - Alfa Aesar". www.alfa.com. Retrieved 2022-08-29.
- ^ Alvarez Roca, Roman; Lemos, Pablo S.; Gracia, Lourdes; Andrés, Juan; Longo, Elson (2016-10-03). "Uncovering the metastable γ-Ag2WO4 phase: a joint experimental and theoretical study". RSC Advances. 7 (10): 5610–5620. Bibcode:2017RSCAd...7.5610R. doi:10.1039/C6RA24692C. hdl:10234/167867.
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