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Nitrate selenite

The nitrate selenites are mixed anion compounds containing distinct nitrate (NO3−)and selenite (SO32−) groups. The compounds are colourless unless coloured by cations.

List

[edit]
formula formula weight crystal system space group unit cell Å volume density comment reference
[Cu(HSeO3)2(NO3)2]2−•2NH4+•NH4NO3 orthorhombic Pnma a=8.8813 b=24.01 c=7.2195 [1]
(RbNO3)2[Cu(HSeO3)2] monoclinic P21/c a=9.2833 b=7.1193 c=9.0315 β=91.643° [2]
Ag5Cu2(NO3)(SeO3)4 1326.26 triclinic P1 a=5.148 b=7.050 c=10.540 α=73.09° β=89.08° γ=88.50° 365.85 5.61 [3]
Cd(HSeO3)NO3 302.38 orthorhombic Pbca a=6.359 b=8.945 c=16.648 Z=8 949.1 4.23 [4]
(CsNO3)[Cu(HSeO3)2] orthorhombic Pnma a=8.891 b=13.859 c=7.249 [2]
Gd(NO3)(Se2O5)•3H2O orthorhombic P212121 a=6.2509 b=7.0944 c=20.747 SHG 0.2 × KDP [5]
Lu(SeO3)(NO3)(H2O) 381.96 orthorhombic Pbcn a=16.151 b=11.854 c=6.795 Z=8 1300.9 3.900 colourless [6]
(TlNO3)[Cu(HSeO3)2] orthorhombic Pnma a=8.7788 b=13.668 c=7.2056 [2]
Pb2(SeO3)(NO3)2 orthorhombic Pmn21 a = 5.4669 b = 10.3277 c = 7.2610 Z = 4 409.96 [7][8]
Pb2(NO2)(NO3)(SeO3) orthorhombic Pmn21 a=5.529 b=10.357 c=6.811 Z=2 [9]
PbCu3(OH)(NO3)(SeO3)3•0.5H2O triclinic P1 a=7.761 b=9.478 c=9.514 α=66.94° β=69.83° γ=81.83° Z=2 [3][10]
Pb2Cu3O2(NO3)2(SeO3)2 orthorhombic Cmc21 a=5.884 b=12.186 c=19.371 Z=4 [3][10]
Pb(OF)Cu3(SeO3)2(NO3) 748.74 R3m a=6.6973 c=18.5548 Z=3 720.75 5.175 dark brown [11]
PbCdF(SeO3)(NO3) orthorhombic Pca21 a=11.121 b=10.366 c=5.3950 Z=4 621.9 5.634 SHG 2.6×KDP band gap 4.42 eV [12]
Bi(SeO3)(NO3) monoclinic C2/c a=15.352 b=4.9112 c=14.101 β=110.79° [13]
(Bi3O2)(SeO3)2(NO3) monoclinic P21/c a=9.9403 b=9.6857 c=10.6864 β=93.115° Z=4 [14]
((CH3)4N)[UO2(NO3)(SeO3)] monoclinic C2/m a = 21.888 b = 6.9501 c = 8.349 β = 97.618° Z = 4 1259.0 2.813 yellow-green [15]
(H2en)[(UO2)(SeO3)(HSeO3)](NO3)·0.5H2O 1316.19 orthorhombic Pbca a = 13.170 b = 11.055 c = 18.009 Z = 4 2621.8 3.334 [16]

References

[edit]
  1. ^ Lafront, A.M.; Trombe, J.C. (June 1995). "'Layered hydrogenselenite' I. Synthesis, structure redetermination of [Cu(HSeO3)2(H2O)2] and determination of [Cu(HSeO3)2(NO3)2]2−·2NH4+,NH4NO3. Structural relationships of these complexes with [Cu(HSeO3)2]". Inorganica Chimica Acta. 234 (1–2): 19–25. doi:10.1016/0020-1693(95)04500-9.
  2. ^ a b c Markovski, Mishel R.; Charkin, Dmitri O.; Siidra, Oleg I.; Nekrasova, Diana O. (2019-12-18). "Copper hydroselenite nitrates ( A + NO 3 ) n [Cu(HSeO 3 ) 2 ] ( A =Rb + , Cs + and Tl + , n =1, 2) related to Ruddlesden – Popper phases". Zeitschrift für Kristallographie - Crystalline Materials. 234 (11–12): 749–756. doi:10.1515/zkri-2019-0036. ISSN 2196-7105. S2CID 208868309.
  3. ^ a b c Effenberger, H. (1991-12-15). "Structure of pentasilver(I) dicopper(II) mononitrate tetraselenite(IV)". Acta Crystallographica Section C Crystal Structure Communications. 47 (12): 2522–2525. Bibcode:1991AcCrC..47.2522E. doi:10.1107/S0108270191006935.
  4. ^ Leskela, Markku; Valkonen, Jussi; Leskela, Tuula (1984). "The crystal structure, thermal behaviour and IR spectrum of cadmium hydrogenselenite nitrate" (PDF). Acta Chemica Scandinavica A. 38: 233–239. doi:10.3891/acta.chem.scand.38a-0233.
  5. ^ Wu, Chao; Li, Longhua; Lin, Lin; Huang, Zhipeng; Humphrey, Mark G.; Zhang, Chi (2020). "Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge". Dalton Transactions. 49 (10): 3253–3259. doi:10.1039/D0DT00116C. hdl:1885/251599. PMID 32096527. S2CID 211477899.
  6. ^ Wu, Chao; Li, Longhua; Lin, Lin; Huang, Zhipeng; Humphrey, Mark G.; Zhang, Chi (2020-04-14). "Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution". Chemistry of Materials. 32 (7): 3043–3053. doi:10.1021/acs.chemmater.0c00034. hdl:1885/251600. ISSN 0897-4756. S2CID 216215995.
  7. ^ Meng, Chang-Yu; Geng, Lei; Chen, Wen-Ting; Wei, Ming-Fang; Dai, Kai; Lu, Hong-Yan; Cheng, Wen-Dan (August 2015). "Syntheses, structures, and characterizations of a new second-order nonlinear optical material: Pb2(SeO3)(NO3)2". Journal of Alloys and Compounds. 640: 39–44. doi:10.1016/j.jallcom.2015.04.021.
  8. ^ Meng, Chang-Yu; Geng, Lei; Chen, Wen-Ting; Wei, Ming-Fang; Dai, Kai; Lu, Hong-Yan; Cheng, Wen-Dan (August 2015). "Syntheses, structures, and characterizations of a new second-order nonlinear optical material: Pb2(SeO3)(NO3)2". Journal of Alloys and Compounds. 640: 39–44. doi:10.1016/j.jallcom.2015.04.021.
  9. ^ Effenberger, Herta (February 1987). "Darstellung und Kristallstruktur von Pb2(NO2)(NO3)(SeO3)". Monatshefte für Chemie Chemical Monthly (in German). 118 (2): 211–216. doi:10.1007/BF00810054. ISSN 0026-9247. S2CID 101945551.
  10. ^ a b Effenberger, Herta (October 1986). "PbCu3(OH)(NO3)(SeO3)3·1/2H2O und Pb2Cu3O2(NO3)2(SeO3)2: Synthese und Kristallstrukturuntersuchung". Monatshefte für Chemie - Chemical Monthly (in German). 117 (10): 1099–1106. doi:10.1007/BF00811322. ISSN 0026-9247. S2CID 99187991.
  11. ^ Zhang, Mengsi; Zhao, Zhiying; Zhang, Wanwan; Li, Jinyang; Huang, Xiaoying; He, Zhangzhen (2020). "Pb(OF)Cu 3 (SeO 3 ) 2 (NO 3 ): a selenite fluoride nitrate with a breathing kagomé lattice". Chemical Communications. 56 (80): 11965–11968. doi:10.1039/D0CC03684F. ISSN 1359-7345. PMID 33033813. S2CID 222235842.
  12. ^ Ma, Yun-Xiang; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2018-09-17). "PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units". Inorganic Chemistry. 57 (18): 11839–11846. doi:10.1021/acs.inorgchem.8b02044. ISSN 0020-1669. PMID 30160946. S2CID 52136440.
  13. ^ Song, Jun-Ling; Qian, Cheng (February 2017). "Syntheses, Crystal Structures, and Properties of Two Quaternary Selenite/Tellurite-Nitrates with Formula of Bi(SeO 3 )(NO 3 ) and Bi 3 (μ 3 -OH)(TeO 3 ) 3 (NO 3 ) 2". ChemistrySelect. 2 (4): 1681–1685. doi:10.1002/slct.201601967. ISSN 2365-6549.
  14. ^ Meng, Chang-Yu; Wei, Ming-Fang; Geng, Lei; Hu, Pei-Qing; Yu, Meng-Xia; Cheng, Wen-Dan (July 2016). "Synthesis, structure, and characterization of two new bismuth(III) selenite/tellurite nitrates: [(Bi3O2)(SeO3)2](NO3) and [Bi(TeO3)](NO3)". Journal of Solid State Chemistry. 239: 46–52. doi:10.1016/j.jssc.2016.04.013.
  15. ^ Liu, Dong-Sheng; Huang, Gan-Sheng; Luo, Qiu-Yan; Xu, Ya-Ping; Li, Xin-Fa (2006-07-01). "Poly[tetramethylammonium [nitratouranyl-μ 3 -selenito]]". Acta Crystallographica Section E: Structure Reports Online. 62 (7): m1584–m1585. doi:10.1107/S1600536806022045. ISSN 1600-5368. S2CID 62743321.
  16. ^ Liu, Dong-Sheng; Kuang, Han-Mao; Chen, Wen-Tong; Luo, Qiu-Yan; Sui, Yan (September 2015). "Synthesis, Structure, and Photoluminescence Properties of an Organically-Templated Uranyl Selenite". Zeitschrift für anorganische und allgemeine Chemie. 641 (11): 2009–2013. doi:10.1002/zaac.201500277. ISSN 0044-2313.
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)−4 RONO2
+CO3
+C2O4 		NO3-
NH4NO3 		HOONO2 FNO3
+F 		Ne
NaNO3 Mg(NO3)2 Al(NO3)3
Al(NO3)−4 		Si P +SO4 ClONO2
+Cl 		Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)2
Fe(NO3)3 		Co(NO3)2
Co(NO3)3 		Ni(NO3)2 CuNO3
Cu(NO3)2 		Zn(NO3)2 Ga(NO3)3 Ge As +SeO3 BrNO3
+Br 		Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 NbO(NO3)3 MoO2(NO3)2 Tc Ru Rh(NO3)3 Pd(NO3)2
Pd(NO3)4 		AgNO3
Ag(NO3)2 		Cd(NO3)2 In(NO3)3 Sn(NO3)4 Sb4O4(OH)2(NO3)2 Te INO3
+IO3 		Xe(NO3)2
CsNO3 Ba(NO3)2 * Lu(NO3)3 Hf(NO3)4 TaO(NO3)3 WO2(NO3)2 ReO3NO3 Os Ir3O(NO3)10 Pt(NO3)2 Au(NO3)3 Hg2(NO3)2
Hg(NO3)2 		TlNO3
Tl(NO3)3 		Pb(NO3)2 Bi(NO3)3
BiO(NO3) 		Po(NO3)4 At Rn
FrNO3 Ra(NO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(NO3)3 Ce(NO3)3
Ce(NO3)4 		Pr(NO3)3 Nd(NO3)3 Pm(NO3)3 Sm(NO3)3 Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy(NO3)3 Ho(NO3)3 Er(NO3)3 Tm(NO3)3 Yb(NO3)3
** Ac(NO3)3 Th(NO3)4 PaO(NO3)3 UO2(NO3)2 Np(NO3)4 Pu(NO3)4 Am(NO3)3 Cm(NO3)3 Bk(NO3)3 Cf(NO3)3 Es Fm Md No
Salts and covalent derivatives of the selenite ion
H2SeO3 He
Li Be BxSexOx C +NO3 O +F Ne
Na2SeO3 Mg Al Si P +SO4 Cl Ar
K Ca Sc Ti V Cr MnSeO3 Fe2(SeO3)3 Co Ni CuSeO3
Cu2OSeO3 		ZnSeO3 Ga Ge As +SeO4 Br Kr
RbHSeO3 Sr Y Zr Nb Mo Tc Ru Rh Pd Ag2SeO3 Cd In Sn Sb Te I Xe
CsHSeO3 Ba * Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
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Nitrate selenite
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