Cerium(IV) perchlorate
  
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| Names | |
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| IUPAC name
Cerium(IV) perchlorate
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Other names
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.034.794 |
| EC Number |
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| Ce(ClO4)4 | |
| Molar mass | 537.92 g/mol |
| Density | 1.556 g/cm−3 (25 °C)[1] |
| Melting point | 725 °C (1,337 °F; 998 K) |
| Hazards | |
| GHS labelling:[2] | |
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| Warning | |
| H272 | |
| P210, P220, P280, P370+P378, P501 | |
| Related compounds | |
Other cations
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Titanium perchlorate, Zirconium perchlorate |
Related compounds
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Cerium(III) perchlorate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Cerium(IV) perchlorate is an inorganic compound composed of cerium and perchloric acid. It has the chemical formula of Ce(ClO4)4.
Uses
[edit]Cerium(IV) perchlorate is used as a catalyst in organic chemistry for the determination of strontium and for cerimetry.[3][4][5][6] It has a very high redox potential at Ce4+/Ce3+ of +1.87 V in 8 M HClO4.[7]
References
[edit]- ^ Sigma-Aldrich Co., product no. (({id))}.
- ^ "Cerium(4+) perchlorate". pubchem.ncbi.nlm.nih.gov.
- ^ Philip L. Fuchs, André B. Charette, Tomislav Rovis, Jeffrey W. Bode (2016), Essential Reagents for Organic Synthesis (in German), John Wiley & Sons, p. 80, ISBN 978-1-119-27983-9
((citation)): CS1 maint: multiple names: authors list (link) - ^ W.J. Mijs, C.R.H.I. de Jonge (2013), Organic Syntheses by Oxidation with Metal Compounds (in German), Springer Science & Business Media, p. 601, ISBN 978-1-4613-2109-5
- ^ E. Gagliardi, E. Wolf: Bestimmung von Strontium mit Cer(IV)-perchlorat. In: Microchimica Acta. 51, 1963, S. 578, doi:10.1007/BF01217587.
- ^ P. H. List, L. Hörhammer (2013), Allgemeiner Teil. Wirkstoffgruppen I (in German), Springer-Verlag, p. 301, ISBN 978-3-642-47985-4
- ^ K.A. Gschneidner, Jr., J.-C.G. Bünzli and V.K. Pecharsky (2006), Handbook on the Physics and Chemistry of Rare Earths (in German), Elsevier, p. 306, ISBN 978-0-08-046672-9
((citation)): CS1 maint: multiple names: authors list (link)
| Cerium(II) | |||
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| Cerium(III) |
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| Cerium(III,IV) |
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| Cerium(IV) | |||
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